Flexibility is the key to tuning the transport properties of fluorinated imide-based ionic liquids

Author:

Philippi Frederik1ORCID,Rauber Daniel2ORCID,Palumbo Oriele3ORCID,Goloviznina Kateryna4,McDaniel Jesse5,Pugh David6ORCID,Suarez Sophia7,Fraenza Carla C.8,Padua Agilio4ORCID,Kay Christopher W. M.29ORCID,Welton Tom1ORCID

Affiliation:

1. Department of Chemistry, Molecular Sciences Research Hub, Imperial College London, White City Campus, London W12 0BZ, UK

2. Department of Chemistry, Saarland University, Campus B2.2, Saarbrücken, Germany

3. Consiglio Nazionale delle Ricerche, Istituto dei Sistemi Complessi, Piazzale Aldo Moro 5, 00185 Rome, Italy

4. Laboratoire de Chimie, École Normale Supérieure de Lyon, CNRS, 69364 Lyon, France

5. School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, Georgia, 30332-0400, USA

6. Department of Chemistry, King's College London, 7 Trinity Street, London SE1 1DB, UK

7. Department of Physics, Brooklyn College of CUNY, Brooklyn, New York, 11210, USA

8. Department of Physics and Astronomy, Hunter College of CUNY, New York, 10065, USA

9. London Centre for Nanotechnology, University College London, 17–19 Gordon Street, London WC1H 0AH, UK

Abstract

The interplay of fluorination, flexibility, and mass affects the transport properties of imide ionic liquids. Here we show how the combination of experimental and theoretical techniques can disentangle such confounding variables.

Funder

Royal Society

Consiglio Nazionale delle Ricerche

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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