Photocatalyzed reductive fluoroalkylation of 2-acetoxyglycals towards the stereoselective synthesis of α-1-fluoroalkyl-C-glycosyl derivatives-Reference-Cited by-同舟云学术

Photocatalyzed reductive fluoroalkylation of 2-acetoxyglycals towards the stereoselective synthesis of α-1-fluoroalkyl-C-glycosyl derivatives

Published:2020 Issue:42 Volume:18 Page:8724-8734
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Mora Flores Erwin W.¹²³⁴⁵,Uhrig María Laura¹⁶³⁷⁸^ORCID,Postigo Al¹²³⁴⁵^ORCID

Affiliation:

1. Universidad de Buenos Aires

2. Facultad de Farmacia y Bioquímica

3. Departamento de Química Orgánica

4. CP1113-Buenos Aires

5. Argentina

6. Facultad de Ciencias Exactas y Naturales

7. Pabellón 2

8. Ciudad Universitaria

Abstract

A benign, efficient, regio- and stereoselective protocol for the syntheses of α-1-fluoroalkyl-C-glycosyl compounds bearing CF₃, C₄F₉, and C₆F₁₃ substituents on the anomeric carbon has been developed.

Funder

Universidad de Buenos Aires

Fondo para la Investigación Científica y Tecnológica

Consejo Nacional de Investigaciones Científicas y Técnicas

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/OB/D0OB01914C

Reference58 articles.

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2. C-Glycosides and Aza-C-Glycosides as Potential Glycosidase and Glycosyltransferase Inhibitors

3. Synthesis of C-Saccharides and Higher Congeners

4. Recent Advances in the Chemical Synthesis of C-Glycosides

5. Recent developments in β-C-glycosides: synthesis and applications

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