Palladium-catalyzed enantioselective domino ring-opening/Hiyama coupling of cyclobutanones: development and application to the synthesis of (+)-herbertene-1,14-diol-Reference-Cited by-同舟云学术

Palladium-catalyzed enantioselective domino ring-opening/Hiyama coupling of cyclobutanones: development and application to the synthesis of (+)-herbertene-1,14-diol

Published:2022 Issue:21 Volume:9 Page:5798-5801
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Gan Wan-Er¹,Cao Jian¹^ORCID,Xu Li-Wen¹²^ORCID

Affiliation:

1. Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Key Laboratory of Organosilicon Material Technology of Zhejiang Province, College of Material, Chemistry and Chemical Engineering, Hangzhou Normal University, Hangzhou, 311121, Zhejiang, P. R. China

2. State Key Laboratory for Oxo Synthesis and Selective Oxidation, Suzhou Research Institute and Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, P. R. China

Abstract

A palladium-catalyzed enantioselective domino ring-opening/Hiyama coupling of cyclobutanones is reported, providing chiral 1-indanones bearing a versatile alkenyl group.

Funder

Natural Science Foundation of Zhejiang Province

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/QO/D2QO01239A

Reference28 articles.

1. Catalytic enantioselective synthesis of quaternary carbon stereocentres

2. Catalytic Enantioselective Construction of Quaternary Stereocenters: Assembly of Key Building Blocks for the Synthesis of Biologically Active Molecules