Cyclometalated C^N diphosphine ruthenium catalysts for Oppenauer-type oxidation/transfer hydrogenation reactions and cytotoxic activity-Reference-Cited by-同舟云学术

Cyclometalated C^N diphosphine ruthenium catalysts for Oppenauer-type oxidation/transfer hydrogenation reactions and cytotoxic activity

Published:2023 Issue:18 Volume:13 Page:5267-5279
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Alessi Dario¹^ORCID,Del Mestre Pierfrancesco²,Aneggi Eleonora¹^ORCID,Ballico Maurizio¹^ORCID,Beltrami Antonio P.²^ORCID,Busato Marta¹^ORCID,Cesselli Daniela²^ORCID,Heidecker Alexandra A.³^ORCID,Zuccaccia Daniele¹^ORCID,Baratta Walter¹^ORCID

Affiliation:

1. Dipartimento di Scienze Agroalimentari, Ambientali e Animali, Università di Udine, Via Cotonificio 108, I-33100 Udine, Italy

2. Dipartimento di Area Medica – Istituto di Anatomia Patologica, Università di Udine, Via Chiusaforte, F3, I-33100 Udine, Italy

3. Inorganic Chemistry/Molecular Catalysis, Department of Chemistry & Catalysis Research Center, TUM, Lichtenbergstraße 4, 85747 Garching b. München, Germany

Abstract

The neutral ruthenium cyclometalated complexes [Ru(C^N)(η2-OAc)(dppb)] proven to be efficient catalysts in Oppenauer-type oxidation and transfer hydrogenation reactions with TOF up to 14 300 h−1 and show cytotoxic activity against U87 cancer cells.

Funder

University of Udine

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CY/D3CY00676J

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3. Gram-scale synthesis of carboxylic acids via catalytic acceptorless dehydrogenative coupling of alcohols and hydroxides at an ultralow Ru loading

4. Iridium-Catalyzed Hydrohydroxyalkylation of Butadiene: Carbonyl Crotylation

5. Electronically tuneable orthometalated RuII–NHC complexes as efficient catalysts for C–C and C–N bond formations via borrowing hydrogen strategy