Synthesis, structure and reactivity of rare-earth metallacarborane alkyls [η1:η5-O(CH2)2C2B9H9]Ln(σ:η1-CH2C6H4-o-NMe2)(THF)2-Reference-Cited by-同舟云学术

Synthesis, structure and reactivity of rare-earth metallacarborane alkyls [η1:η5-O(CH2)2C2B9H9]Ln(σ:η1-CH2C6H4-o-NMe2)(THF)2

Published:2015 Issue:14 Volume:44 Page:6630-6637
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Yang Jingying¹²³⁴⁵,Xie Zuowei¹²³⁴⁵

Affiliation:

1. Department of Chemistry

2. Center of Novel Functional Molecules and State Key Laboratory of Synthetic Chemistry

3. The Chinese University of Hong Kong

4. Shatin, NT

5. China

Abstract

Rare-earth metallacarborane alkyls have been prepared for the first time, which react with unsaturated organic molecules to give either mono- or di-insertion products depending on the nature of the substrates.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT00095E

Reference34 articles.

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3. Mono(cyclopentadienyl) Complexes of the Rare-Earth Metals

4. Organometallic catalysts for copolymerization of cyclic olefins

5. Synthesis and Structural Chemistry of Non-Cyclopentadienyl Organolanthanide Complexes

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