Ammonia synthesis by the reductive N–N bond cleavage of hydrazine using an air-stable, phosphine-free ruthenium catalyst-Reference-Cited by-同舟云学术

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Ammonia synthesis by the reductive N–N bond cleavage of hydrazine using an air-stable, phosphine-free ruthenium catalyst

Published:2024 Issue:4 Volume:60 Page:416-419
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Mohanty Aisa¹,Rout Smruti Rekha²,Dandela Rambabu²,Daw Prosenjit¹^ORCID

Affiliation:

1. Department of Chemical Sciences, Indian Institute of Science Education and Research Berhampur, Transit Campus, (Govt. ITI Building), Engg. School Junction, Berhampur 760010, Odisha, India

2. Department of Industrial and Engineering Chemistry, Institute of Chemical Technology, Bhubaneswar 751013, Odisha, India

Abstract

An air-stable, phosphine-free ruthenium-based molecular catalyst is developed for the efficient reduction of hydrazine to ammonia using suitable reductant and proton pairs.

Funder

Science and Engineering Research Board

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CC/D3CC04490D

Reference23 articles.

1. Structure−Function Relationships of Alternative Nitrogenases

2. Structural Basis of Biological Nitrogen Fixation

3. Mechanism of Molybdenum Nitrogenase

4. Catalytic N2-to-NH3 (or -N2H4) Conversion by Well-Defined Molecular Coordination Complexes

5. Intermediates Trapped during Nitrogenase Reduction of N⋮N, CH3−NNH, and H2N−NH2

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