Photochemical halogen-bonding assisted carbothiophosphorylation reactions of alkenyl and 1,3-dienyl bromides-Reference-Cited by-同舟云学术

Photochemical halogen-bonding assisted carbothiophosphorylation reactions of alkenyl and 1,3-dienyl bromides

Published:2023 Issue:44 Volume:14 Page:12767-12773
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Piedra Helena F.¹^ORCID,Gebler Victoria¹^ORCID,Valdés Carlos¹^ORCID,Plaza Manuel¹^ORCID

Affiliation:

1. Departamento de Química Orgánica e Inorgánica, Instituto Universitario de Química Organometálica “Enrique Moles”, Centro de Innovación en Química Avanzada (ORFEO-CINQA), Universidad de Oviedo, Julián Clavería 8, 33006 Oviedo, Spain

Abstract

The photochemical halogen-bonding assisted alkenylation and dienylation of phosphoro(di)thioate diesters under batch and continuous flow is disclosed. Mechanistic studies support the formation of the halogen-bonding complex and the radical pathway.

Funder

Agencia Estatal de Investigación

Fundación para el Fomento en Asturias de la Investigación Científica Aplicada y la Tecnología

Erasmus+

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D3SC05263J

Reference58 articles.

1. Engineered C–S Bond Construction