Alkali metal complexes having sterically bulky bis-iminopyrrolyl ligands – control of dimeric to monomeric complexes
Author:
Affiliation:
1. Department of Chemistry
2. Indian Institute of Technology Hyderabad
3. India
4. Department of Applied Chemistry
5. Indian School of Mines
6. Dhanbad
Abstract
Alkali metal salts of {(CHPh2)2-pyr} and {(CPh3)2-pyr} were prepared and in the molecular structures of these complexes a nuclearity shift from the dimer to monomer were observed due to the substitutions of CHPh2 to CPh3 groups in imine nitrogen of the ligand.
Funder
Council of Scientific and Industrial Research
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/RA/C6RA13437H
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