Direct synthesis of alkenyl iodides via indium-catalyzed iodoalkylation of alkynes with alcohols and aqueous HI

Author:

Wu Chao12345,Wang Zheng1234,Hu Zhan1234,Zeng Fei1234,Zhang Xing-Yu1234,Cao Zhong5674,Tang Zilong89104,He Wei-Min123411ORCID,Xu Xin-Hua111274ORCID

Affiliation:

1. Hunan Provincial Engineering Research Center for Ginkgo biloba

2. Hunan University of Science and Engineering

3. Yongzhou 425100

4. China

5. Hunan Provincial Key Laboratory of Materials Protection for Electric Power and Transportation

6. Changsha University of Science and Technology

7. Changsha

8. Key Laboratory of Theoretical Organic Chemistry and Functional Molecule of Ministry of Education

9. Hunan University of Science and Technology

10. Xiangtan 411201

11. State Key Laboratory of Chemo/Biosensing and Chemometrics

12. Hunan University

Abstract

A simple and efficient method has been developed for the synthesis of alkenyl iodides through indium-catalyzed iodoalkylation of alkynes with alcohols and aqueous HI under mild conditions.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Hunan Province

Education Department of Hunan Province

Construct Program of the Key Discipline in Hunan Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

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