Synthesis and supramolecular organization of the iodide and triiodides of a polycyclic adamantane-based diammonium cation: the effects of hydrogen bonds and weak I⋯I interactions

Author:

Mezentsev-Cherkes Ivan A.1234,Shestimerova Tatiana A.1234,Medved'ko Aleksei V.534,Kalinin Mikhail A.1234,Kuznetsov Alexey N.12346ORCID,Wei Zheng1789,Dikarev Evgeny V.1789ORCID,Vatsadze Sergey Z.12345ORCID,Shevelkov Andrei V.1234ORCID

Affiliation:

1. Department of Chemistry

2. Lomonosov Moscow State University

3. 119991 Moscow

4. Russia

5. N.D. Zelinsky Institute of Organic Chemistry RAS

6. N. S. Kurnakov Institute of General and Inorganic Chemistry RAS

7. University at Albany

8. Albany

9. USA

Abstract

Adamantane-like divalent building blocks and iodide or polyiodide anions combine into supramolecular architectures with the help of various noncovalent forces ranging from strong hydrogen bonds to secondary and weak I⋯I interactions.

Funder

Russian Science Foundation

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

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