Nucleophilic substitution in benzylic thiophosphinyl and thiophosphonyl chlorides: the contribution of elimination–addition pathways with methylenethioxophosphorane (thiophosphene) intermediates-Reference-Cited by-同舟云学术

Nucleophilic substitution in benzylic thiophosphinyl and thiophosphonyl chlorides: the contribution of elimination–addition pathways with methylenethioxophosphorane (thiophosphene) intermediates

Published:1994 Issue:10 Volume: Page:2101-2107
ISSN:0300-9580
Container-title:J. Chem. Soc., Perkin Trans. 2
language:en
Short-container-title:J. Chem. Soc., Perkin Trans. 2

Author:

Coogan Michael P.,Harger Martin J. P.

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/1994/P2/P29940002101

Reference53 articles.

1. Evidence for a methylenethioxophosphorane (thiophosphene) intermediate in nucleophilic substitution at a benzylthiophosphonyl centre

2. A theoretical study of model substituted phosphoranes, PH4X: apicophilicities, geometries, and electron densities

3. An ‘open’ transition state in the transfer reaction of a neutral phosphoryl group between phenolate anions

4. Do pentacoordinate oxyphosphorane intermediates always exist?

5. Phosphonates as mimics of phosphate biomolecules: ab initio calculations on tetrahedral ground states and pentacoordinate intermediates for phosphoryl transfer

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