Spin–orbit charge-transfer intersystem crossing in heavy-atom-free orthogonal covalent boron-dipyrromethene heterodimers-Reference-Cited by-同舟云学术

Spin–orbit charge-transfer intersystem crossing in heavy-atom-free orthogonal covalent boron-dipyrromethene heterodimers

Published:2023 Issue:36 Volume:25 Page:24386-24394
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Wang Zeming¹,Ma Lin¹,Zhao Hongmei¹,Wan Yan²^ORCID,Zhang Xian-Fu³,Li Yang¹,Kuang Zhuoran¹^ORCID,Xia Andong¹^ORCID

Affiliation:

1. State Key Laboratory of Information Photonic and Optical Communications, and School of Science, Beijing University of Posts and Telecommunications (BUPT), Beijing 100876, P. R. China

2. College of Chemistry, Beijing Normal University, Beijing 100875, P. R. China

3. Department of Materials Science and Engineering, Southern University of Science and Technology, Shenzhen, Guangdong Province 518055, P. R. China

Abstract

The strong inter-chromophoric interactions, sizeable spin–orbit coupling strength, and limited direct charge recombination realized by low structural rigidity optimize the triplet generation based on the SOCT-ISC mechanism in BODIPY heterodimers.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Beijing Municipality

Beijing University of Posts and Telecommunications

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CP/D3CP01934A

Reference65 articles.

1. Heavy-Atom-Free Photosensitizers: From Molecular Design to Applications in the Photodynamic Therapy of Cancer