A visible-light-driven molecular motor based on barbituric acid

Author:

Kuntze Kim12,Pooler Daisy R. S.1ORCID,Di Donato Mariangela34ORCID,Hilbers Michiel F.5,van der Meulen Pieter1,Buma Wybren Jan56ORCID,Priimagi Arri2ORCID,Feringa Ben L.1ORCID,Crespi Stefano17ORCID

Affiliation:

1. Stratingh Institute for Chemistry, University of Groningen, Nijenborgh 4, 9746 AG Groningen, The Netherlands

2. Faculty of Engineering and Natural Sciences, Tampere University, FI-33101 Tampere, Finland

3. European Laboratory for Non Linear Spectroscopy (LENS), via N. Carrara 1, 50019 Sesto Fiorentino, Italy

4. ICCOM-CNR, via Madonna del Piano 10, 50019 Sesto Fiorentino, FI, Italy

5. Van't Hoff Institute for Molecular Sciences, University of Amsterdam, Science Park 904, 1098 XH, Amsterdam, The Netherlands

6. Institute for Molecules and Materials, FELIX Laboratory, Radboud University, Toernooiveld 7c, 6525 ED, Nijmegen, The Netherlands

7. Department of Chemistry, Ångström Laboratory, Uppsala University, Box 523, 751 20 Uppsala, Sweden

Abstract

Yeehaw! The rotation of a visible-light-driven molecular motor based on barbituric acid is tamed by a hydrogen bonding “lasso” mechanism between its serendipitously-formed tertiary hydroxy stereocentre and its lower half carbonyl groups.

Funder

H2020 European Research Council

Ministerie van Onderwijs, Cultuur en Wetenschap

H2020 Marie Skłodowska-Curie Actions

Vetenskapsrådet

Academy of Finland

Horizon 2020 Framework Programme

Rijksuniversiteit Groningen

Suomen Kulttuurirahasto

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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