The interface microenvironment mediates the emission of a semiconductor nanocluster via surface-dopant-involving direct charge transfer

Author:

Wang Zhiqiang12,Ma Hao1,Zhang Jiaxu12,Lan Yingjia2,Liu Jia-Xing1,Yuan Shang-Fu1ORCID,Zhou Xiao-Ping1ORCID,Li Xiaohong2,Qin Chaochao3,Li Dong-Sheng4ORCID,Wu Tao12ORCID

Affiliation:

1. College of Chemistry and Materials Science, Guangdong Provincial Key Laboratory of Functional Supramolecular Coordination Materials and Applications, Jinan University, Guangzhou 510632, China

2. College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, Jiangsu 215123, China

3. Henan Key Laboratory of Infrared Materials & Spectrum Measures and Applications, School of Physics, Henan Normal University, Xinxiang 453007, China

4. College of Materials and Chemical Engineering, Hubei Provincial Collaborative Innovation Center for New Energy Microgrid, Key Laboratory of Inorganic Nonmetallic Crystalline and Energy Conversion Materials, China Three Gorges University, Yichang, Hubei 443002, China

Abstract

Interface microenvironment mediated surface-Mn2+-involving direct charge transfer with interfacial alkylamines was for the first time revealed by using an atomically precise semiconductor nanocluster model with uniform near-surface Mn2+ ions.

Funder

National Natural Science Foundation of China

Higher Education Discipline Innovation Project

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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