Strong magnetic exchange coupling in Ln<sub>2</sub> metallocenes attained by the <i>trans</i>-coordination of a tetrazinyl radical ligand-Reference-Cited by-同舟云学术

Strong magnetic exchange coupling in Ln₂ metallocenes attained by the trans-coordination of a tetrazinyl radical ligand

Published:2023 Issue:14 Volume:10 Page:4197-4208
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Mavragani Niki¹^ORCID,Kitos Alexandros A.¹^ORCID,Hrubý Jakub²,Hill Stephen²³^ORCID,Mansikkamäki Akseli⁴^ORCID,Moilanen Jani O.⁵^ORCID,Murugesu Muralee¹^ORCID

Affiliation:

1. Department of Chemistry and Biomolecular Sciences, University of Ottawa, Ontario K1N 6N5, Canada

2. National High Magnetic Field Laboratory, Florida State University, Tallahassee, Florida 32310, USA

3. Department of Physics, Florida State University, Tallahassee, Florida 32306, USA

4. NMR Research Unit, University of Oulu, P.O. Box 300, 90014 Oulu, Finland

5. Department of Chemistry, Nanoscience Centre, University of Jyväskylä, P.O. Box 35, FI-40014, Finland

Abstract

One of the strongest Ln-rad magnetic coupling was attained in a family of dinuclear Ln metallocenes via the trans coordination mode of a tetrazinyl-based radical bridge, with the Tb(iii) and Dy(iii) analogues exhibiting SMM behaviour.

Funder

University of Ottawa

Canada Foundation for Innovation

Natural Sciences and Engineering Research Council of Canada

Stavros Niarchos Foundation

U.S. Department of Energy

National Science Foundation

Florida Department of State

Academy of Finland

Oulun Yliopisto

Publisher

Royal Society of Chemistry (RSC)