Carbocationic polymerization of isoprene using cumyl initiators: progress in understanding side reactions-Reference-Cited by-同舟云学术

Carbocationic polymerization of isoprene using cumyl initiators: progress in understanding side reactions

Published:2015 Issue:73 Volume:5 Page:59218-59225
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Ouardad Samira¹²³⁴⁵,Wirotius Anne-Laure¹²³⁴⁵,Kostjuk Sergei⁶⁷⁸,Ganachaud François⁹²¹⁰¹¹¹²,Peruch Frédéric¹²³⁴⁵

Affiliation:

1. Univ. Bordeaux

2. CNRS

3. Bordeaux INP

4. LCPO

5. UMR 5629

6. Research Institute for Physical Chemical Problems of the Belarusian State University

7. 220030 Minsk

8. Belarus

9. Univ Lyon

10. INSA-Lyon

11. IMP

12. UMR5223

Abstract

The cationic polymerization of isoprene using cumyl chloride/B(C₆F₅)₃ and cumyl ether/TiCl₄ systems was investigated in dichloromethane or in dichloromethane/methylcyclohexane mixtures varying the polymerization conditions.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/RA/C5RA08557H

Reference22 articles.

1. Polyisoprene synthesized via cationic polymerization: State of the art

2. Bio-inspired cationic polymerization of isoprene and analogues: state-of-the-art

3. Natural rubber biosynthesis—A living carbocationic polymerization?

4. Cationation of dimethylallyl alcohols by B(C6 F5 )3 as models of the (Re)initiation reaction in the bio-inspired cationic polymerization of isoprene

5. Biomimetic carbocationic polymerizations III: Investigation of isoprene polymerization initiated by dimethyl allyl bromide

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