Unveiling photoinduced electron transfer in cobalt(iii)-R-pyridine complexes anchored to anatase nanocrystals: photoluminescence and magnetic studies

Author:

Sundaram Ganeshraja Ayyakannu1ORCID,Anbalagan Krishnamoorthy2ORCID,Wadaan Mohammad Ahmad3,Rajamoni Jagan4,Karthikeyan Vaithinathan5

Affiliation:

1. Department of Research Analytics, Saveetha Dental College and Hospitals, Saveetha Institute of Medical and Technical Sciences, Poonamallee High Road, Chennai, Tamil Nadu, 600 077, India

2. Department of Chemistry, Pondicherry University, Kalapet, Pondicherry, 605 014, India

3. Department of Zoology, College of Science, King Saud University, P. O. Box. 2455, Riyadh, 11451, Saudi Arabia

4. Department of Chemistry and Biochemistry, University of Missouri, St. Louis, MO, 63121, USA

5. School of Science and Technology, Hong Kong Metropolitan University, Ho Man Tin, Hong Kong

Abstract

This article demonstrates the synthesis of mixed ligand complexes of cis-[Co(tn)2(Rpy)Br]Br2via a mechanochemical approach. Their ferromagnetic properties and efficient electron transfer to Co(iii) using TiO2 under UV light are confirmed.

Funder

College of Food and Agriculture Sciences, King Saud University

UGC-DAE Consortium for Scientific Research, University Grants Commission

Publisher

Royal Society of Chemistry (RSC)

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