Diboron-controlled product selectivity switch in copper-catalyzed decarboxylative substitutions of alkynyl cyclic carbonates-Reference-Cited by-同舟云学术

Diboron-controlled product selectivity switch in copper-catalyzed decarboxylative substitutions of alkynyl cyclic carbonates

Published:2021 Issue:24 Volume:8 Page:6950-6961
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Pei Guojing¹,Chen Hui¹,Xu Wan¹,Chen Tao²^ORCID,Li Juan¹^ORCID

Affiliation:

1. College of Chemistry and Materials Science, Guangdong Provincial Key Laboratory of Functional Supramolecular Coordination Materials and Applications, Jinan University, Guangzhou, Guangdong 510632, P. R. China

2. SCNU Environmental Research Institute, Guangdong Provincial Key Laboratory of Chemical Pollution and Environmental Safety & MOE Key Laboratory of Theoretical Chemistry of Environment, South China Normal University, Guangzhou 510006, China

Abstract

DFT calculations were performed to explore the mechanisms, origins of diboron-controlled divergent product selectivity and stereoselectivity in the copper-catalyzed decarboxylative substitution of alkynyl cyclic carbonates.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Guangdong Province

Guangzhou Municipal Science and Technology Project

Jinan University

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/QO/D1QO01411K

Reference108 articles.