Modulation of electronic and redox properties in phenolate-rich cobalt(iii) complexes and their implications for catalytic proton reduction-Reference-Cited by-同舟云学术

Modulation of electronic and redox properties in phenolate-rich cobalt(iii) complexes and their implications for catalytic proton reduction

Published:2015 Issue:7 Volume:44 Page:3454-3466
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Basu Debashis¹²³⁴,Allard Marco M.¹²³⁴,Xavier Fernando R.¹²³⁴,Heeg Mary Jane¹²³⁴,Schlegel H. Bernhard¹²³⁴,Verani Claudio N.¹²³⁴

Affiliation:

1. Department of Chemistry

2. Wayne State University

3. Detroit

4. USA

Abstract

The redox, spectroscopic and catalytic activity of a series of cobalt complexes with phenolate-rich environments was investigated. The complex [Co^III(L^Cl)MeOH] shows considerable proton reduction in MeCN:HOAc with TON = 10.8.

Funder

Advanced Research Projects Agency - Energy

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C4DT03337J

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