Redox-neutral synthesis of π-allylcobalt complexes from alkenes for aldehyde allylation <i>via</i> photoredox catalysis-Reference-Cited by-同舟云学术

Redox-neutral synthesis of π-allylcobalt complexes from alkenes for aldehyde allylation via photoredox catalysis

Published:2022 Issue:23 Volume:24 Page:9027-9032
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Zhang Dandan¹,Li Haoyu¹,Guo Zhuowen¹,Chen Yuqing¹,Yan Huaipu¹,Ye Zenghui²,Zhang Fengzhi²^ORCID,Lu Binghui³,Hao Erjun³^ORCID,Shi Lei¹³^ORCID

Affiliation:

1. Zhang Dayu School of Chemistry, Dalian University of Technology, Dalian, Liaoning, 116024, China

2. School of Pharmaceutical Sciences, Hangzhou Medical College, Hangzhou, Zhejiang, 310059, China

3. School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang, Henan, 453007, China

Abstract

This work reports the first visible-light mediated cobalt-catalyzed aldehyde allylation with simple alkenes to produce homo-allylic alcohols. This novel strategy directly uses easily available unactivated alkenes as allyl sources instead of pre-synthesized allylic halides.

Funder

Henan Normal University

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/GC/D2GC02990A

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