How does ammonia bind to the oxygen-evolving complex in the S2state of photosynthetic water oxidation? Theoretical support and implications for the W1 substitution mechanism-Reference-Cited by-同舟云学术

How does ammonia bind to the oxygen-evolving complex in the S2state of photosynthetic water oxidation? Theoretical support and implications for the W1 substitution mechanism

Published:2016 Issue:46 Volume:18 Page:31551-31565
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Guo Yu¹²³⁴,He Lan-Lan¹²³⁴,Zhao Dong-Xia¹²³⁴,Gong Li-Dong¹²³⁴,Liu Cui¹²³⁴,Yang Zhong-Zhi¹²³⁴

Affiliation:

1. School of Chemistry and Chemical Engineering

2. Liaoning Normal University

3. Dalian 116029

4. People's Republic of China

Abstract

The mechanistic study shows that NH₃substitutes W1 rather than O5 of the OEC in the S₂state and leaves in the S₄′ state.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CP/C6CP05725J

Reference136 articles.

1. Photosynthesis online

2. Transition metals in plant photosynthesis

3. Photosystem II: The Reaction Center of Oxygenic Photosynthesis

4. Oxygen evolving complex in Photosystem II: Better than excellent

5. Why did Nature choose manganese to make oxygen?

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