Origin of intergranular Li metal propagation in garnet-based solid electrolyte by direct electronic structure analysis and performance improvement by bandgap engineering

Author:

Kim Ju-Sik1234,Kim Hyunseok1234,Badding Michael567,Song Zhen567,Kim Kihong8234,Kim Yongsu8234,Yun Dong-Jin8234,Lee Dongwook8234,Chang Jaemyung567,Kim Sewon1234,Im Dongmin1234,Park Seongyong8234,Kim Seong Heon9101112,Heo Sung8234ORCID

Affiliation:

1. Next-generation Battery Lab

2. Samsung Advanced Institute of Technology

3. Suwon-si

4. Republic of Korea

5. Corning Incorporated

6. Corning

7. USA

8. Analytical Engineering Group

9. Department of Physics

10. Myongji University

11. Yongin 17058

12. Korea

Abstract

The mechanism of Li dendrite formation for Ta-doped LLZO (LLZTO) was investigated by examining the electronic structure and the laser annealing of LLZTO was performed as a bandgap engineering method to suppress the Li dendrite formation.

Funder

Ministry of Science and ICT, South Korea

Myongji University

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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