Mg(<scp>i</scp>)–Fe(–<scp>ii</scp>) and Mg(0)–Mg(<scp>i</scp>) covalent bonding in the MgnFe(CO)4− (n = 1, 2) anion complexes: an infrared photodissociation spectroscopic and theoretical study-Reference-Cited by-同舟云学术

Mg(i)–Fe(–ii) and Mg(0)–Mg(i) covalent bonding in the Mg_nFe(CO)₄⁻ (n = 1, 2) anion complexes: an infrared photodissociation spectroscopic and theoretical study

Published:2023 Issue:11 Volume:25 Page:7697-7703
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Jin Xiaoyang¹,Wang Guanjun¹^ORCID,Zhou Mingfei¹^ORCID

Affiliation:

1. Collaborative Innovation Center of Chemistry for Energy Materials, Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysts and Innovative Materials, Fudan University Shanghai, Shanghai 200438, China

Abstract

Heteronuclear magnesium–iron complexes MgFe(CO)4− and Mg2Fe(CO)4− are characterized by infrared photodissociation spectroscopy and theoretical calculations and shown to contain an electron-sharing Mg(i)–Fe(–ii) σ bond and a weak covalent Mg(0)–Mg(i) σ bond.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CP/D2CP05719K

Reference65 articles.

1. Metal–metal bonds in biology

2. Metal–Metal Bonds in Catalysis

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