Size dependence of efficiency of PbS quantum dots in NiO-based dye sensitised solar cells and mechanistic charge transfer investigation

Author:

Raissi Mahfoudh12345,Sajjad Muhammad T.678910ORCID,Pellegrin Yann12345,Roland Thomas Jean678910ORCID,Jobic Stéphane1112131415,Boujtita Mohammed12345,Ruseckas Arvydas678910,Samuel Ifor D. W.678910ORCID,Odobel Fabrice12345ORCID

Affiliation:

1. CEISAM

2. Chimie Et Interdisciplinarité

3. Synthèse

4. Analyse

5. Modélisation

6. Organic Semiconductor Centre

7. SUPA

8. School of Physics and Astronomy

9. University of St Andrews

10. St Andrews

11. Institut des Matériaux Jean Rouxel

12. Université de Nantes

13. CNRS

14. 2

15. 44322 Nantes cedex 03

Abstract

A low driving force (−0.3 eV) is sufficient for PbS quantum dots to inject holes into NiO, and the excitons in PbS decay by both reductive and oxidative quenching.

Funder

Engineering and Physical Sciences Research Council

H2020 European Research Council

Agence Nationale de la Recherche

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science

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