Tailoring non-fullerene acceptors using selenium-incorporated heterocycles for organic solar cells with over 16% efficiency

Author:

Yu Han12345,Qi Zhenyu12345,Zhang Jianquan12345,Wang Zhen678910,Sun Rui11121314,Chang Yuan12345,Sun Huiliang3151614,Zhou Wentao12345,Min Jie11121314ORCID,Ade Harald678910,Yan He12345ORCID

Affiliation:

1. Department of Chemistry

2. Hong Kong Branch of Chinese National Engineering Research Center for Tissue Restoration and Reconstruction

3. Hong Kong University of Science and Technology

4. Kowloon

5. Hong Kong

6. Department of Physics

7. Organic and Carbon Electronics Laboratories (ORaCEL)

8. North Carolina State University

9. Raleigh

10. USA

11. The Institute for Advanced Studies

12. Wuhan University

13. Wuhan 430072

14. China

15. Shenzhen Research Institute

16. Shenzhen 518057

Abstract

The selenium substitution strategy was applied to develop two new A′-DAD-A′-type small molecular acceptors. The resulting selenium-incorporated molecules exhibit red-shifted absorption and an enhanced photon response, leading to high device efficiencies of over 16%.

Funder

U.S. Department of Energy

National Natural Science Foundation of China

Science, Technology and Innovation Commission of Shenzhen Municipality

Innovation and Technology Commission;

National Basic Research Program of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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