Photochemical reactions of a diamidocarbene: cyclopropanation of bromonaphthalene, addition to pyridine, and activation of sp<sup>3</sup> C

Photochemical reactions of a diamidocarbene: cyclopropanation of bromonaphthalene, addition to pyridine, and activation of sp³ C–H bonds

Published:2023 Issue:29 Volume:14 Page:7867-7874
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Perera Tharushi A.¹,Taylor William V.¹,Gildner M. Brenton¹^ORCID,Reinheimer Eric W.²^ORCID,Ito Sho³^ORCID,Nelson Anna¹,Yost Shane R.¹,Hudnall Todd W.¹^ORCID

Affiliation:

1. Department of Chemistry and Biochemistry, Texas State University, 601 University Dr, San Marcos, TX, 78666, USA

2. Rigaku Americas Corporation, 9009 New Trails Dr, The Woodlands, TX 77381, USA

3. Rigaku Corporation, 3-9-12, Matsubara, Akishima, Tokyo 196-8666, Japan

Abstract

Unprecedented photochemical reactions for the diamidocarbene 1 including the double cyclopropanation of 1-bromonaphthalene, the double addition to pyridine, and the activation of sp3 C–H bonds of alkanes are reported.

Funder

National Science Foundation

Welch Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D2SC05122B

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