Excited-state symmetry breaking in quadrupolar pull–push–pull molecules: dicyanovinyl <i>vs.</i> cyanophenyl acceptors-Reference-Cited by-同舟云学术

Excited-state symmetry breaking in quadrupolar pull–push–pull molecules: dicyanovinyl vs. cyanophenyl acceptors

Published:2023 Issue:34 Volume:25 Page:22689-22699
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Verma Pragya¹^ORCID,Tasior Mariusz²,Roy Palas³^ORCID,Meech Stephen R.³^ORCID,Gryko Daniel T.²^ORCID,Vauthey Eric¹^ORCID

Affiliation:

1. Department of Physical Chemistry, University of Geneva, 30 Quai Ernest-Ansermet, CH-1211, Geneva 4, Switzerland

2. Institute of Organic Chemistry, Polish Academy of Sciences, 01-224 Warsaw, Poland

3. School of Chemistry, University of East Anglia, Norwich Research Park, Norwich NR4 7TJ, UK

Abstract

Excited-state symmetry breaking is only observed in multipolar dyes with weaker electron accepting groups. This unexpected result can be rationalised in terms of a subtle balance between solvation energy and inter-branch electronic coupling.

Funder

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

Université de Genève

Narodowe Centrum Nauki

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CP/D3CP02810K

Reference80 articles.

1. Two-Photon Laser Scanning Fluorescence Microscopy

2. Multicolor two-photon light-sheet microscopy

3. Two-Photon Fluorescence Microscopy at Extremely Low Excitation Intensity: The Power of Quantum Correlations

4. Multiphoton Fabrication

5. Ultrafast multi-focus 3-D nano-fabrication based on two-photon polymerization

Cited by 7 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Excited-State Symmetry Breaking and Localization in a Noncentrosymmetric Electron Donor–Acceptor–Donor Molecule;The Journal of Physical Chemistry Letters;2024-08-06

2. Femtosecond stimulated Raman spectroscopy;Nature Reviews Methods Primers;2024-05-23

3. Excited-State Symmetry Breaking in Solvent Mixtures;The Journal of Physical Chemistry Letters;2024-02-26

4. Controlling the symmetry breaking charge transfer extent in excited quadrupolar molecules by tuning the locally excited state;The Journal of Chemical Physics;2024-02-02

5. Excited-state symmetry breaking is an ultrasensitive tool for probing microscopic electric fields;Chemical Science;2024