Deoxygenation of heterocyclic <i>N</i>-oxides employing iodide and formic acid as a sustainable reductant-Reference-Cited by-同舟云学术

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Deoxygenation of heterocyclic N-oxides employing iodide and formic acid as a sustainable reductant

Published:2024 Issue:21 Volume:48 Page:9424-9428
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Cruz-Jiménez Alicia Elvira¹,Argumedo-Castrejón Paola Alejandra¹,Mateus-Ruiz Jeferson B.¹,Lucas-Rosales Victor A.²^ORCID,Valle-González Octavio Adrián¹^ORCID,Jiménez-Halla J. Oscar C.²,Luján-Montelongo J. Armando¹^ORCID

Affiliation:

1. Departamento de Química, Centro de Investigación y de Estudios Avanzados (Cinvestav) Av. Instituto Politécnico Nacional 2508 San Pedro Zacatenco, 07360 Ciudad de México, Mexico

2. Departamento de Química, División de Ciencias Naturales y Exactas, Sede Noria Alta, Universidad de Guanajuato, Noria Alta s/n, C.P, 36050, Guanajuato, Gto., Mexico

Abstract

We present a novel deoxygenation method of heterocyclic N-oxides catalyzed by iodide (MgI2) and regenerated by formic acid. Mechanistic insights are provided through DFT investigations.

Funder

Consejo Nacional de Ciencia y Tecnología

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/NJ/D4NJ00913D

Reference66 articles.

1. Quinoline, quinazoline, and acridone alkaloids

2. Pyridine Scaffolds, Phenols and Derivatives of Azo Moiety: Current Therapeutic Perspectives

3. A comprehensive review on the biological interest of quinoline and its derivatives

4. Natural isoquinoline alkaloids: binding aspects to functional proteins, serum albumins, hemoglobin, and lysozyme

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