Mixed-valent neptunium oligomer complexes based on cation–cation interactions
Author:
Affiliation:
1. Helmholtz-Zentrum Dresden-Rossendorf (HZDR)
2. Institute of Resource Ecology
3. 01328 Dresden
4. Germany
Abstract
Mixing Np(iv) and Np(v) (as neptunyl(v)) results in the formation of tri- and tetranuclear oligomer complexes based on cation–cation interactions (CCIs), indicating the potential of CCIs to expand the oligomer/cluster chemistry of actinides.
Funder
Bundesministerium für Bildung und Forschung
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT01056D
Reference37 articles.
1. Actinide Colloids and Particles of Environmental Concern
2. Clusters of Actinides with Oxide, Peroxide, or Hydroxide Bridges
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4. Recent Advances in Aqueous Actinide Chemistry and Thermodynamics
5. The crystal chemistry of uranium carboxylates
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1. The crystal and coordination chemistry of neptunium in all its oxidation states: An expanded structural hierarchy of neptunium compounds;Coordination Chemistry Reviews;2021-10
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