Role of Lewis and Brønsted acid sites in resorcinol tert-butylation over heteropolyacid-based catalysts-Reference-Cited by-同舟云学术

Role of Lewis and Brønsted acid sites in resorcinol tert-butylation over heteropolyacid-based catalysts

Published:2020 Issue:23 Volume:10 Page:7984-7997
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Pezzotta Chiara¹²³⁴^ORCID,Marakatti Vijaykumar S.¹²³⁴^ORCID,Gaigneaux Eric M.¹²³⁴^ORCID

Affiliation:

1. Institute of Condensed Matter and Nanosciences (IMCN)

2. Université catholique de Louvain

3. 1348 Louvain-la-Neuve

4. Belgium

Abstract

Investigating Keggin heteropolyacid embedded in SiO₂, TiO₂ and ZrO₂ showed that both Brønsted (B) and Lewis (L) acid sites are needed to achieve the alkylation of resorcinol with MTBE. An optimum B to L site ratio allows maximizing the performance.

Funder

Fonds De La Recherche Scientifique - FNRS

H2020 Marie Skłodowska-Curie Actions

Fonds pour la Formation à la Recherche dans l’Industrie et dans l’Agriculture

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CY/D0CY01030H

Reference39 articles.

1. Recent advances in the industrial alkylation of aromatics: new catalysts and new processes