Direct amination of benzene to aniline with H2O2 and NH3·H2O over Cu/SiO2 catalyst
Author:
Affiliation:
1. Key Laboratory of Green Chemistry and Technology
2. Ministry of Education
3. College of Chemistry
4. Sichuan University
5. Chengdu, China
Abstract
Cu/S-1 catalyst activated the N–H bond of NH3 and C–H bond of benzene leading to the formation of aniline.
Publisher
Royal Society of Chemistry (RSC)
Subject
Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2014/CY/C4CY00432A
Reference48 articles.
1. Palladium-Catalyzed Coupling of Ammonia and Lithium Amide with Aryl Halides
2. Selective Palladium-Catalyzed Arylation of Ammonia: Synthesis of Anilines as Well as Symmetrical and Unsymmetrical Di- and Triarylamines
3. Efficient copper-catalyzed coupling of aryl chlorides, bromides and iodides with aqueous ammonia
4. Direct aromatic-ring amination by aqueous ammonia with a platinum loaded titanium oxide photocatalyst
5. Sodium metavanadate catalyzed one-step amination of benzene to aniline with hydroxylamine
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