Visible-light-induced mesoporous graphitic carbon nitride-catalyzed trifluoromethylation and perfluoroalkylation of 4-aminocoumarins

Author:

Li Ning-Bo1,Gu Shuo2,Hu Chu-Qian1,Wang Yu-Xin1,Zhou Xue1,Qiao Jie1,Jiang Jun3,Ji Hong-Tao3,He Wei-Min3ORCID

Affiliation:

1. School of Basic Medical Sciences, Shanxi Medical University, Taiyuan, 030001, China

2. School of Pharmaceutical Sciences, Shanxi Medical University, Taiyuan, 030001, China

3. School of Chemistry and Chemical Engineering, University of South China, Hengyang 421001, China

Abstract

A heterogeneous mesoporous graphitic carbon nitride (mpg-C3N4) photocatalytic 3-trifluoromethylation/perfluoroalkylation of 4-aminocoumarins was realized from 4-aminocoumarins and CnF2n+1SO2Na under mild conditions.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Shanxi Province

Scientific Research Foundation of Hunan Provincial Education Department

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

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