Tunable intramolecular H-bonding promotes benzoic acid activity in polymerization: inspiration from nature-Reference-Cited by-同舟云学术

Tunable intramolecular H-bonding promotes benzoic acid activity in polymerization: inspiration from nature

Published:2017 Issue:41 Volume:8 Page:6398-6406
ISSN:1759-9954
Container-title:Polym. Chem.
language:en
Short-container-title:Polym. Chem.

Author:

Xu Jiaxi¹²³⁴,Yang Kun¹²³⁴,Li Zhenjiang¹²³⁴⁵^ORCID,Liu Jingjing¹²³⁴,Sun Herui¹²³⁴,Xu Songquan¹²³⁴,Wang Haixin¹²³⁴,Guo Tianfo¹²³⁴^ORCID,Dong He¹²³⁴,Guo Kai¹²³⁴⁵^ORCID

Affiliation:

1. College of Biotechnology and Pharmaceutical Engineering

2. Nanjing Tech University

3. Nanjing

4. China

5. State Key Laboratory of Materials-Oriented Chemical Engineering

Abstract

Intramolecular H-bonding of ortho-amido group(s) tuned benzoic acid into strong Brønsted acid active in ring-opening polymerizations of lactones and trimethylene carbonate at room temperature in solutions.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2017/PY/C7PY01451A

Reference43 articles.

1. The return of a forgotten polymer—Polycaprolactone in the 21st century

2. Activated Monomer Cationic Polymerization of Lactones and the Application to Well-Defined Block Copolymer Synthesis with Seven-Membered Cyclic Carbonate

3. Controlled/Living Ring-Opening Polymerization of δ-Valerolactone Using Triflylimide as an Efficient Cationic Organocatalyst

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