Synthesis of quinolinyl-based pincer copper(ii) complexes: an efficient catalyst system for Kumada coupling of alkyl chlorides and bromides with alkyl Grignard reagents

Author:

Pandiri Hanumanprasad12345,Gonnade Rajesh G.673ORCID,Punji Benudhar12345ORCID

Affiliation:

1. Organometallic Synthesis and Catalysis Group

2. Chemical Engineering Division

3. India

4. Academy of Scientific and Innovative Research (AcSIR)

5. New Delhi 110 020

6. Centre for Material Characterization. CSIR–National Chemical Laboratory (CSIR–NCL)

7. Pune – 411 008

Abstract

Well-defined quinolinamide-based pincer copper complexes have been developed and demonstrated in the Kumada coupling reaction of nonactivated alkyl chlorides and bromides with alkyl magnesium chloride.

Funder

Science and Engineering Research Board

Council of Scientific and Industrial Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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