Electronic spectroscopy of homo- and heterometallic binuclear coinage metal phosphine complexes in isolation

Author:

Schmitt Marcel J. P.1ORCID,Kruppa Sebastian V.1ORCID,Walg Simon P.1,Thiel Werner R.1ORCID,Klopper Wim2ORCID,Riehn Christoph13ORCID

Affiliation:

1. Department of Chemistry, Rheinland-Pfälzische Technische Universität (RPTU) Kaiserslautern-Landau, Erwin-Schrödinger Str. 53, 67663 Kaiserslautern, Germany

2. Institute of Physical Chemistry, Karlsruhe Institute of Technology (KIT), Fritz-Haber-Weg 2, 76131 Karlsruhe, Germany

3. Research Center OPTIMAS, Erwin-Schrödinger Str. 46, 67663 Kaiserslautern, Germany

Abstract

Electronic transitions ofin situsynthesized homo- and heterobinuclear coinage metal complexes revealing spectral blue-shifts in correlation to increasing metal–metal distance.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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