Bimolecular fusion of [Pd3(μ-CN-C6H3Me2-2,6)3(CN-C6H3Me2-2,6)3] induced by Ph2GeH2: formation of the redox-active Pd6Ge2 complex-Reference-Cited by-同舟云学术

Bimolecular fusion of [Pd3(μ-CN-C6H3Me2-2,6)3(CN-C6H3Me2-2,6)3] induced by Ph2GeH2: formation of the redox-active Pd6Ge2 complex

Published:2019 Issue:22 Volume:48 Page:7541-7545
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Koizumi Take-aki¹²³⁴⁵,Tanaka Kimiya¹²³⁴⁵,Tsuchido Yoshitaka¹²³⁴⁵,Tanabe Makoto¹²³⁴⁵,Ide Tomohito⁶⁷⁸⁹⁵^ORCID,Osakada Kohtaro¹²³⁴⁵^ORCID

Affiliation:

1. Laboratory for Chemistry and Life Science

2. Institute of Innovative Research

3. Tokyo Institute of Technology

4. Yokohama 226-8503

5. Japan

6. Department of Chemical Science and Engineering

7. National Institute of Technology

8. Tokyo College

9. Tokyo

Abstract

The reaction of Ph₂GeH₂ with a planar tripalladium(0) complex, [Pd₃(μ-CN-C₆H₃Me₂-2,6)₃(CN-C₆H₃Me₂-2,6)₃], selectively afforded a hexagonal bipyramidal Pd₆Ge₂ complex, [Pd₆(μ-GePh₂)₂(CN-C₆H₃Me₂-2,6)₈(μ-CN-C₆H₃Me₂-2,6)₂].

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT00814D

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3. Optical, Electrochemical, and Catalytic Properties of the Unsaturated Host Pd3(dppm)3(CO)2+and Pd4(dppm)4(H)2+2Clusters: An Overview

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