Dioxygen reacts with metal–carbon bonds in thorium dialkyls to produce bis(alkoxides)-Reference-Cited by-同舟云学术

Dioxygen reacts with metal–carbon bonds in thorium dialkyls to produce bis(alkoxides)

Published:2019 Issue:17 Volume:48 Page:5569-5573
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Settineri Nicholas S.¹²³⁴⁵^ORCID,Shiau Angela A.¹²³⁴,Arnold John¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. University of California

3. Berkeley

4. USA

5. Chemical Sciences Division

Abstract

Reaction of molecular O₂ with thorium alkyl complexes supported by amidinates and guanidinates generates thorium alkoxides via O₂ insertion into thorium-carbon bonds.

Funder

Lawrence Berkeley National Laboratory

Nuclear Energy University Program

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT00811J

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