Transition metal-free hydrodefluorination of acid fluorides and organofluorines by Ph3GeH promoted by catalytic [Ph3C][B(C6F5)4]-Reference-Cited by-同舟云学术

Transition metal-free hydrodefluorination of acid fluorides and organofluorines by Ph3GeH promoted by catalytic [Ph3C][B(C6F5)4]

Published:2019 Issue:73 Volume:55 Page:10852-10855
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Hayatifar Ardalan¹²³⁴^ORCID,Borrego Alejandro⁵⁶⁴,Bosek David⁵⁶⁴^ORCID,Czarnecki Matthew⁵⁶⁴,Derocher Gabriel⁵⁶⁴,Kuplicki Adam⁵⁶⁴,Lytle Erik⁵⁶⁴,Padilla Jonas⁵⁶⁴,Paroly Charles⁵⁶⁴,Tubay Gillian⁵⁶⁴,Vyletel Jackson⁵⁶⁴,Weinert Charles S.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Oklahoma State University

3. Stillwater

4. USA

5. University of Detroit Jesuit High School and Academy

6. Detroit

Abstract

The germylium cation [Ph₃Ge]⁺converts aryl and aliphatic acid fluorides directly to their corresponding aldehydes. Hydrodefluorination of organofluorine compounds by [Ph₃Ge]⁺was also observed.

Funder

National Science Foundation

National Institutes of Health

Division of Chemistry

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CC/C9CC05075B

Reference39 articles.

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