Axially-chiral boramidine for detailed (chir)optical studies-Reference-Cited by-同舟云学术

Axially-chiral boramidine for detailed (chir)optical studies

Published:2024 Issue:17 Volume:15 Page:6530-6535
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Saleh Nidal¹^ORCID,Sucre-Rosales Estefanía²,Zinna Francesco³^ORCID,Besnard Céline⁴^ORCID,Vauthey Eric²^ORCID,Lacour Jérôme¹^ORCID

Affiliation:

1. Department of Organic Chemistry, University of Geneva, Quai Ernest Ansermet 30, 1211 Geneva 4, Switzerland

2. Department of Physical Chemistry, University of Geneva, Quai Ernest Ansermet 30, 1211 Geneva 4, Switzerland

3. Dipartimento di Chimica e Chimica Industriale, University of Pisa, Via G. Moruzzi 13, 56124 Pisa, Italy

4. Laboratory of Crystallography, University of Geneva, Quai Ernest Ansermet 24, 1211 Geneva 4, Switzerland

Abstract

An axially-chiral boramidine displays UV-absorption, deep-blue fluorescence (Φ up to 94%), and |10−3| gabs and glum. Deactivation pathways of the emissive state to triplet excited states, involving increased spin–orbit coupling, are identified.

Funder

Université de Genève

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D4SC00870G

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