Changes in magnetic order through two consecutive dehydration steps of metal-phosphonate diamond chains

Author:

Su Yan-Hui12345,Jia Jia-Ge12345,Huang Xin-Da12345,Feng Jian-Shen12345,Bao Song-Song12345,Ren Min12345,Kurmoo Mohamedally678910,Zheng Li-Min12345ORCID

Affiliation:

1. State Key Laboratory of Coordination Chemistry

2. School of Chemistry and Chemical Engineering

3. Collaborative Innovation Center of Advanced Microstructures

4. Nanjing University

5. Nanjing 210023

6. Université de Strasbourg

7. Institut de Chimie de Strasbourg

8. CNRS-UMR7177

9. Strasbourg Cedex 67070

10. France

Abstract

M3II(hpdpH)2(H2O)6·4H2O (M = Co, Ni) experience identical two-step dehydration processes associated with drastic magnetic changes from paramagnet to antiferromagnet/metamagnetic to ferrimagnet for M = Co, and from antiferromagnet to antiferromagnet to ferrimagnet for M = Ni.

Funder

National Natural Science Foundation of China

National Basic Research Program of China

Centre National de la Recherche Scientifique

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Reference62 articles.

1. A. Clearfield , Progress in Inorganic Chemistry , Wiley , New York , 1998 , vol. 47 , pp. 371–510

2. Metal Phosphonate Chemistry: From Synthesis to Applications , ed. A. Clearfield and K. Demadis , the Royal Society of Chemistry , 2012

3. New Directions in Metal Phosphonate and Phosphinate Chemistry

4. Metal-organic solids derived from arylphosphonic acids

5. Metal–Organic Frameworks assembled from tetraphosphonic ligands and lanthanides

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