Supramolecularly modulated carbon-centered radicals: toward selective oxidation from benzyl alcohol to aldehyde-Reference-Cited by-同舟云学术

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Supramolecularly modulated carbon-centered radicals: toward selective oxidation from benzyl alcohol to aldehyde

Published:2024 Issue:40 Volume:60 Page:5286-5289
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Tang Xingchen¹,Mei Shan¹,Xu Jiang-Fei¹^ORCID,Zhang Xi¹^ORCID

Affiliation:

1. Key Laboratory of Organic Optoelectronics & Molecular Engineering, Department of Chemistry, Tsinghua University, Beijing 100084, China

Abstract

Host–guest interaction of cucurbit[7]uril is used to adjust the reactivity of ketyl radicals and benzoyl radicals, therefore enhancing the aldehyde selectivity of photo-induced oxidation of benzyl alcohol.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CC/D4CC01240B

Reference50 articles.

1. Catalysis of Radical Reactions: A Radical Chemistry Perspective

2. Radicals: Reactive Intermediates with Translational Potential

3. Recent advances in the chemistry of ketyl radicals

4. Centenary Lecture. The pursuit of selectivity in radical reactions

5. Radical philicity and its role in selective organic transformations

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