Tuning the reorganization energy of electron transfer in supramolecular ensembles – metalloporphyrin, oligophenylenevinylenes, and fullerene – and the impact on electron transfer kinetics

Author:

Stangel Christina1234,Schubert Christina5678,Kuhri Susanne5678,Rotas Georgios91011,Margraf Johannes T.567812,Regulska Elzbieta131415,Clark Timothy1251617,Torres Tomás1819202120,Tagmatarchis Nikos91011,Coutsolelos Athanassios G.1234,Guldi Dirk M.5678

Affiliation:

1. Department of Chemistry

2. University of Crete

3. Laboratory of Bioinorganic Chemistry

4. 71003 Heraklion, Greece

5. Department of Chemistry and Pharmacy

6. Interdisciplinary Center for Molecular Materials (ICMM)

7. Friedrich-Alexander-Universität Erlangen-Nuernberg

8. 91058 Erlangen, Germany

9. Theoretical and Physical Chemistry Institute

10. National Hellenic Research Foundation

11. Athens 11635, Greece

12. Computer Chemie Centrum

13. Institute of Chemistry

14. University of Bialystok

15. 15-399 Białystok, Poland

16. Friedrich-Alexander-Universitaet Erlangen-Nuernberg

17. 91052 Erlangen, Germany

18. Departamento de Quimica Organica

19. Universidad Autonoma de Madrid

20. 28049-Madrid, Spain

21. IMDEA-Nanociencia

Abstract

Strong distance dependence of the total reorganization energy in C60-PPV1-pyr·ZnPs is in stark contrast to the distance independence for covalently linked conjugates.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science

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