Chemical bonding and dynamic structural fluxionality of a boron-based Al2B8 binary cluster: the robustness of a doubly 6π/6σ aromatic [B8]2− molecular wheel-Reference-Cited by-同舟云学术

Chemical bonding and dynamic structural fluxionality of a boron-based Al₂B₈ binary cluster: the robustness of a doubly 6π/6σ aromatic [B₈]²⁻ molecular wheel

Published:2023 Issue:3 Volume:13 Page:1964-1973
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Yue Rong-Xin¹,Gao Shu-Juan¹²,Han Peng-Fei¹,Zhai Hua-Jin¹^ORCID

Affiliation:

1. Nanocluster Laboratory, Institute of Molecular Science, Shanxi University, Taiyuan 030006, China

2. Department of Chemistry and Chemical Engineering, Lvliang University, Lvliang 033000, China

Abstract

Boron-based Al2B8 cluster assumes a sandwich structure. The Al2 unit floats above and below a boron wheel, featuring intriguing dynamic fluxionality.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/RA/D2RA07268H

Reference48 articles.

1. Boron Cluster Cations: Transition from Planar to Cylindrical Structures

2. Planar-to-tubular structural transition in boron clusters: B20 as the embryo of single-walled boron nanotubes

3. Aromaticity of Planar Boron Clusters Confirmed

4. A Photoelectron Spectroscopic and Theoretical Study of B16− and B162−: An All-Boron Naphthalene

5. The B35 Cluster with a Double-Hexagonal Vacancy: A New and More Flexible Structural Motif for Borophene

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