Modifying the properties of 4f single-ion magnets by peripheral ligand functionalisation

Author:

Pedersen Kasper S.123,Ungur Liviu456,Sigrist Marc12378,Sundt Alexander91011,Schau-Magnussen Magnus123,Vieru Veacheslav456,Mutka Hannu78,Rols Stephane78,Weihe Høgni123,Waldmann Oliver91011,Chibotaru Liviu F.456,Bendix Jesper123,Dreiser Jan1213141516

Affiliation:

1. Department of Chemistry

2. University of Copenhagen

3. DK-2100 Copenhagen, Denmark

4. Theory of Nanomaterials Group

5. Katholieke Universiteit Leuven

6. 3001 Leuven, Belgium

7. Institut Laue-Langevin

8. 38042 Grenoble Cedex 9, France

9. Physikalisches Institut

10. Universität Freiburg

11. 79104 Freiburg, Germany

12. Ecole Polytechnique Fédérale de Lausanne

13. Institute of Condensed Matter Physics

14. 1015 Lausanne and Swiss Light Source

15. Paul Scherrer Institut

16. , Switzerland

Abstract

Three Er(iii) single-ion magnets which differ in the peripheral ligand sphere but exhibit similar first coordination spheres show profoundly different inelastic neutron scattering spectra and magnetic properties.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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