Influence of hydrophobic residues on the binding of CB[7] toward diammonium ions of common ammonium⋯ammonium distance

Author:

Cao Liping1234,Škalamera Đani5678,Zavalij Peter Y.1234,Hostaš Jiří9101112,Hobza Pavel910111213,Mlinarić-Majerski Kata5678,Glaser Robert14151617,Isaacs Lyle1234

Affiliation:

1. Department of Chemistry and Biochemistry

2. University of Maryland

3. College Park

4. USA

5. Department of Organic Chemistry and Biochemistry

6. Ruđer Bošković Institute

7. 10000 Zagreb

8. Croatia

9. Institute of Organic Chemistry and Biochemistry

10. Academy of Sciences of the Czech Republic

11. 16610 Praha 6

12. Czech Republic

13. Regional Center of Advanced Technologies and Materials

14. Department of Chemistry

15. Ben-Gurion University of the Negev

16. Beer-Sheva 84105

17. Israel

Abstract

We report that diammonium ion guests with common N+⋯N+ spacings but different core hydrophobic moieties exhibit remarkably different affinities toward CB[7].

Funder

Czech Science Foundation

Division of Chemistry

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

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