A novel Mn4+-activated fluoride red phosphor Cs30(Nb2O2F9)9(OH)3·H2O:Mn4+ with good waterproof stability for WLEDs-Reference-Cited by-同舟云学术

A novel Mn⁴⁺-activated fluoride red phosphor Cs₃₀(Nb₂O₂F₉)₉(OH)₃·H₂O:Mn⁴⁺ with good waterproof stability for WLEDs

Published:2022 Issue:18 Volume:10 Page:7049-7057
ISSN:2050-7526
Container-title:Journal of Materials Chemistry C
language:en
Short-container-title:J. Mater. Chem. C

Author:

Chen Yingyuan¹,Liu Feilong¹,Zhang Ziwang¹^ORCID,Hong Junyu¹,Molokeev Maxim S.²³⁴,Bobrikov Ivan A.⁵,Shi Jianxin¹^ORCID,Zhou Jianbang¹⁶,Wu Mingmei¹^ORCID

Affiliation:

1. MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry/School of Marine Sciences, Sun Yat-Sen University, Guangzhou 510275/Zhuhai 519082, P. R. China

2. Laboratory of Crystal Physics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk 660036, Russia

3. Siberian Federal University, Krasnoyarsk 660041, Russia

4. Department of Physics, Far Eastern State Transport University, Khabarovsk 680021, Russia

5. Frank Laboratory of Neutron Physics, Joint Institute for Nuclear Research, Dubna 141980, Russia

6. Institute of Resources Utilization and Rare Earth Development, Guangdong Academy of Sciences, Guangzhou 510650, P. R. China

Abstract

Due to the presence of Nb5+, a Mn4+-doped compound (denoted as CNOFM) shows very good waterproof stability, even without any surface modification. Warm WLEDs with a high color rendering index have been fabricated using the CNOFM red phosphor.

Funder

National Natural Science Foundation of China

Basic and Applied Basic Research Foundation of Guangdong Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/TC/D2TC00132B

Reference56 articles.

1. Enhanced luminous efficiency of deep red emitting K2SiF6:Mn4+ phosphor dependent on KF ratio for warm-white LED

2. Optimized photoluminescence of red phosphor K2TiF6:Mn4+synthesized at room temperature and its formation mechanism