Mechanistic origins of accelerated hydrogenation of mixed alkylaromatics by synchronised adsorption over Rh/SiO<sub>2</sub>-Reference-Cited by-同舟云学术

Mechanistic origins of accelerated hydrogenation of mixed alkylaromatics by synchronised adsorption over Rh/SiO₂

Published:2023 Issue:6 Volume:8 Page:1341-1348
ISSN:2058-9883
Container-title:Reaction Chemistry & Engineering
language:en
Short-container-title:React. Chem. Eng.

Author:

Cherkasov Nikolay¹²,Asano Shusaku³^ORCID,Tsuji Yuta⁴^ORCID,Okazawa Kazuki⁵,Yoshizawa Kazunari⁵^ORCID,Miyamura Hiroyuki⁶,Hayashi Jun-ichiro³,Kunitsa Alexander A.⁷,Jackson S. David⁸^ORCID

Affiliation:

1. School of Engineering, University of Warwick, Coventry, CV4 7AL, UK

2. Stoli Chem Ltd, Wellesbourne Campus, Wellesbourne, Coventry, CV35 9EF, UK

3. Institute for Materials Chemistry and Engineering, Kyushu University, Kasuga 816-8580, Japan

4. Faculty of Engineering Sciences, Kyushu University, Kasuga 816-8580, Japan

5. Institute for Materials Chemistry and Engineering, Kyushu University, Fukuoka 819-0395, Japan

6. Interdisciplinary Research Center for Catalytic Chemistry, National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba, Ibaraki 305-8565, Japan

7. Department of Chemistry, University of Illinois at Urbana-Champaign, Urbana, Illinois 61801, USA

8. Department of Chemistry, Joseph Black Building, University of Glasgow, Glasgow G12 8QQ, UK

Abstract

We have studied the unique reaction acceleration phenomenon in the mixture and discussed the limitations of the Langmuir–Hinshelwood model for a solid-catalysed reaction.

Funder

Japan Society for the Promotion of Science

Japan Science and Technology Agency

Royal Society

Publisher

Royal Society of Chemistry (RSC)

Subject

Fluid Flow and Transfer Processes,Process Chemistry and Technology,Chemical Engineering (miscellaneous),Chemistry (miscellaneous),Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/RE/D3RE00032J

Reference45 articles.

1. Hydrogenation of bio-oil into higher alcohols over Ru/Fe3O4-SiO2 catalysts

2. Zero trans fats from soybean oil and fully hydrogenated soybean oil: Physico-chemical properties and food applications

3. Catalytic hydrogenolysis of larix bark proanthocyanidins in ionic liquids produces UV blockers with potential for use in cosmetics

4. Polysilane-Immobilized Rh–Pt Bimetallic Nanoparticles as Powerful Arene Hydrogenation Catalysts: Synthesis, Reactions under Batch and Flow Conditions and Reaction Mechanism

5. Simultaneous electrocatalytic hydrogenation of aldehydes and phenol over carbon-supported metals

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