Aromatic C-nitrosation by a copper(ii)–nitrosyl complex
Author:
Affiliation:
1. Department of Chemistry
2. Indian Institute of Technology
3. Guwahati
4. India
Abstract
Addition of nitric oxide to the methanol solution of copper(ii) complex of 4-amino-3-hydroxy-1-sulphonic acid, resulted in the reduction of Cu(ii) center through unstable copper(ii)-nitrosyl intermediate. The reduction was accompanied with simultaneous C-nitrosation of the aromatic ring of the ligand.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2015/DT/C4DT02689F
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