Silver-initiated radical ring expansion/fluorination of ethynyl cyclobutanols: efficient synthesis of monofluoroethenyl cyclopentanones-Reference-Cited by-同舟云学术

Silver-initiated radical ring expansion/fluorination of ethynyl cyclobutanols: efficient synthesis of monofluoroethenyl cyclopentanones

Published:2016 Issue:23 Volume:18 Page:6236-6240
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Tian Qingshan¹²³⁴,Chen Bin¹²³⁴,Zhang Guozhu¹²³⁴

Affiliation:

1. State Key Laboratory of Organometallic Chemistry Shanghai Institute of Organic Chemistry

2. Chinese Academy of Sciences

3. Shanghai 200032

4. P. R. China

Abstract

A stereoselective synthesis of β-halogenated 2-methylenecyclopentanones via silver-catalyzed formal ring expansion using water as the cosolvent is described.

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/GC/C6GC02656G

Reference66 articles.

1. Fluorine in Pharmaceuticals: Looking Beyond Intuition

2. Fluorine in medicinal chemistry

3. Fluorine in Pharmaceutical Industry: Fluorine-Containing Drugs Introduced to the Market in the Last Decade (2001–2011)

4. Synthesis of Polyfluoroalkyl Aza-Polycyclic Aromatic Hydrocarbons Enabled by Addition of Perfluoroalkyl Radicals onto Vinyl Azides

5. P. Kirsch , Modern Fluoroorganic Chemiry: Synthesis, Reactivity, Applications, Wiley-VCH, Weinheim, 2013, and references cited therein

Cited by 41 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Hydroxy Group-Enabled Regio- and Stereoselective Hydroalkylation of Alkynyl Cyclobutanol via Palladium-Catalyzed C–C Bond Activation of Cyclopropanol: A One-Step Access to Vinyl Cyclobutanols;Organic Letters;2024-07-22

2. Silver‐Catalyzed Carbofluorination of Olefins and α‐Fluoroolefins with Carbamoyl Radicals;Chemistry – A European Journal;2024-06-18

3. Non-Classical Molecular Activation by Phosphines and N-Heterocyclic Carbenes and Its Application to Catalytic Reactions;Bulletin of the Chemical Society of Japan;2023-07-28

4. Emergence of Ag as a Catalyst of Choice for Fluorination and Trifluoromethylation Reactions;ChemCatChem;2023-07-18

5. Cascade Alkenylation/Intramolecular Friedel–Crafts Alkylation: High Selectivity at the C7-Position of BINOL;The Journal of Organic Chemistry;2023-04-03