Rotationally resolved electronic spectroscopy of the rotamers of 1,3-dimethoxybenzene

Author:

Schneider Michael1234,Wilke Martin1234,Hebestreit Marie-Luise1234,Ruiz-Santoyo José Arturo5678,Álvarez-Valtierra Leonardo5678ORCID,Yi John T.9101112,Meerts W. Leo1314151617,Pratt David W.9181912,Schmitt Michael1234ORCID

Affiliation:

1. Heinrich-Heine-Universität

2. Institut für Physikalische Chemie I

3. D-40225 Düsseldorf

4. Germany

5. División de Ciencias e Ingenierías

6. Universidad de Guanajuato-Campus León

7. León

8. Mexico

9. Department of Chemistry

10. Winston-Salem State University

11. Winston-Salem

12. USA

13. Radboud University

14. Institute for Molecules and Materials

15. Felix Laboratory

16. Toernooiveld 7c

17. 6525 ED Nijmegen

18. University of Vermont

19. Burlington

Abstract

Only two of three different rotamers of 1,3-dimethoxybenzene can be observed in molecular beam experiments. The missing rotamer adopts a non-planar structure upon electronic excitation and is absent due to small Franck–Condon factors.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Reference45 articles.

1. Atomic and Molecular Beam Methods, ed. G. Scoles, Oxford University Press, New York, Oxford, 1988, vol. 1

2. Atomic and Molecular Beam Methods, ed. G. Scoles, Oxford University Press, New York, Oxford, 1992, vol. 2

3. Conformational interconversions in supersonic jets: Matrix IR spectroscopy and model calculations

4. Relaxation of conformers and isomers in seeded supersonic jets of inert gases

5. The missing conformers of glycine and alanine: relaxation in seeded supersonic jets

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